Sh = kcL/DAB — dimensionless convective mass transfer. The mass-transfer analogue of the Nusselt number; relates convective mass transfer coefficient to molecular diffusivity over a characteristic length.
Mass Transfer · Dimensionless NumberSolve for:
Typical: gas-phase 10⁻³–10⁻¹ m/s · liquid-phase 10⁻⁶–10⁻⁴ m/s
Definition:
Sh = 1 means convection provides no enhancement over pure molecular diffusion. Higher Sh means the convective mass transfer coefficient is that many times larger than the pure-diffusion reference DAB/L.
Heat–mass transfer analogy (Nu → Sh, Pr → Sc):
Replace Pr with Sc and h with kc in any forced-convection Nu correlation to get the corresponding Sh correlation.
Common Sh correlations:
| Geometry / regime | Correlation | Validity |
|---|---|---|
| Laminar pipe, const-c | Sh = 3.66 | Fully developed, Re < 2300 |
| Laminar pipe, const-flux | Sh = 4.36 | Fully developed, Re < 2300 |
| Turbulent pipe | Sh = 0.023 Re⁰·⁸ Sc⅓ | Re > 10 000, 0.6 < Sc < 3000 |
| Flat plate, laminar avg | Sh = 0.664 Re^½ Sc^⅓ | Re < 5×10⁵, Sc > 0.6 |
| Sphere (Ranz-Marshall) | Sh = 2 + 0.6 Re^½ Sc^⅓ | 2 < Re < 200, 0.6 < Sc < 250 |
| Pure diffusion (stagnant) | Sh = 2 | Re → 0 (sphere), or stagnant film |
Sh vs Nu vs Bi: